LEAFSCAN now has a screen that shows which
Balancing MOSFETs are enabled at any given time. I have seen them activate at any time, even after charging completes.
While they will work anytime automatically, you will not get the full benefit of a top balance without an occasional full charge, but then again, if you only ever charge to 80%, then you probably don't mind losing 15% anyway.
Here's the summation:
You don't need to do anything special for the pack to maintain itself within certain bounds, but if you want to insure that all capacity will be usable if you perform a full charge (~95% SoC), then I recommend you allow a full charge occasionally to allow the balancing to peak your pack properly. I recommend leaving the charger connected overnight after your full charge to allow for additional peaking. I've seen it restart charging up to 5 times so far.
Leaving your pack at full charge for 24 hours once in a while is not going to degrade anything, and in fact, will give you more usable range as it will stay in balance better.
-Phil