If not too late to the discussion ........
Nissan Long-life (blue) coolant and Zerex/Valvoline multi-vehicle Asian formula (red) are both silicate, borates and amines free.
There may be a difference in the presence or absence, or amount, of nitrates and nitrites and maybe even phosphates.
The multi-vehicle formula obviously tries to have all the bases covered in terms of not having any potentially harmful ingredients to any one make/model but may through necessity miss out on having something that one automaker considers desirable for their vehicle's cooling systems.
From the color they chose, and being aware of North American market penetration, I would expect the Zerex Asian formula to be closer (or identical) to Toyota's requirements than to Nissan's.
The main reasons for not using a multi-vehicle coolant I suggest are:
1. it may have the effect of reducing the useful life of your original fill by a few years
2. it may turn the original blue color into something that doesn't look like any known coolant which could impact future service decisions
The Leaf uses the same Nissan blue long-life pre-mixed coolant that other current Nissans use. There is not a special coolant for the Leaf.
Re. the 3 coolant caps under the hood in the 2011/12 years:
- two of them are pressurized tank caps and one is a non-pressurized reservoir (recommended one to use for filling or topping-off)
- the other two caps are mainly for excess pressure venting but also can be used for confirming level
- the Owner's Manual gives the capacity for the heater system separately but am not sure how you would fill this in isolation
- filling/topping off at the frontmost reservoir cap should bring the main cooling system and the cabin heater system up to snuff
For a DIY drain and fill, be aware that flushing the system out with water (preferably distilled) will mean that some water remains in the system. When using a pre-mix coolant this does present a problem in achieving the required 50/50 proportion.