Generally speaking (meaning I haven't heard of a car yet where this was not the case, but I'm not an expert) the parking brake (putting the shifter into "park") ONLY locks the drive wheels. The separate "emergency brake" (i.e. hand brake, foot brake, sometimes called parking brake as well) is different, and can/will usually lock the rear wheels as well. You should be able to engage/disengage the e-brake manually, or with some button mechanism.
FYI, the volt's e-brake is controlled by a switch, and you have to hold the switch in/out to engage/disengage the e-brake. I do NOT like that, as it takes a couple seconds of holding the button to do either. I see it as something that I would just never do, because it's a hassle rather than stepping on an e-brake pedal or pulling up the hand brake. Not to mention, how are you going to do that in an emergency situation if your power brakes fail? But I guess that's a rant for another thread so I'll stop there.
The other option is that the Leaf should have a "neutral" setting as well. I'm pretty sure the test mule that I drove had that, although I didn't try it out. Not sure if that would disengage the drive wheels from the motor, allowing for towing, but I would think would avoid any potential "automatic locking" of the rear wheels.
Of course, this entire thread will be obsolete as soon as they get around to publishing the owners manual. Every car out there has a towing section in the owners manual, Leaf should be no different. All will be explained there, even if it's a one-word: "Don't"!