CUBldr97 said:
Why is charging to 100% bad?
Li-ion batteries work by intercalation, which is the process of physically stuffing ions into an electrode and then pulling them out. Li batteries are not 'chemical' batteries in this sense.
The steadier the population of Li ions you leave stuffed in the electrodes, the more mechanically robust they remain. The electrodes physically expand a little as they are stuffed with ions, and shrink again when they are pulled out. The physical structure of the electrode may actually collapse if you pull too many of the ions out, and will force the electrode to swell when you stuff them back in. It should therefore be clear that the less charging and discharging, the longer the battery electrodes will last because they are under a more regular mid-range of stress in those circumstances. Imagine that the springs of your car are regularly extended and compressed to their limits on every bump, then you can imagine they would fail long before springs that ride over a road with gentle oscillations.
Of course, you cannot fear to charge up your battery to 100%, it is designed to do it. But there is no question that it will last longer if you avoid doing so*. You should charge to 100% every so often, though, and this is because of battery management rather than life expectancy. Charging to full will allow the battery to recalibrate its various function, and will 'level' the cells because following repetitive part-charges the cell voltages will begin to drift and some can end up significantly higher or lower than others, which is an issue not usually corrected unless and until all the cells are taken up to their maximum nominal voltage. (You might also note an excess of power drawn while the battery is cell-levelling, because what it is doing is 'shunting' (bypassing) the cells that have hit their full cell voltage, while the others with lower voltages get charged up further. This shunting will waste some of the charge current, so the battery will heat up during this phase, so you might notice a significantly lower 'wall-to-wheel' efficiency during such charges.)
*The exception to not charging to 100% is when you first get the battery, because, as you may gather from the description above, charging to 100% physically stretches the electrode. Within reason, a little bit of extra 'stretching' will therefore improve capacity, but there is no particular reason to do this deliberately as you will, inevitably, need to charge to 100% enough times in normal use that this will happen anyway as a matter of course.
When the battery is drained then if any cells started off quite low then they'll be the first to hit the minimum allowable voltage. I do not actually know what strategy Leaf has for dealing with one defective cell/module, but possibly (?) it only takes one low cell to tell the BMS that the battery is flat? Does anyone know how the BMS deals with this? Are the low cells shunted, and if so how many get shunted before the battery is regarded as 'flat'? Tesla run a 'battery conditioning' process - is this just warming the cells up, or perhaps do they have a way to charge up the low cells from the remainder?